USER TALK: COMPLEXITY IN STRUCTURES DRIVEN BY ION DYNAMICS
Solid ion conductors are fascinating materials for energy conversion and storage applications. Due to their intrinsic properties and especially their high ion mobility in the lattice they are often characterized by complex crystal structures, polymorphism and the loss symmetry during structural phase transitions. This last aspect often causes twinning and demands the collection of precise data and the usage of group-subgroups relations to solve and understand their crystal structures. Beside the structural features of a selection of solid ion conductors discussed in this presentation also intriguing electronic property changes can occur that are closely related to the ion dynamics and structure changes upon heating or cooling of such materials. In this talk we present a series of copper and silver ion conductors that also show reasonable electronic conductivities which characterize them as mixed-conducting semiconductors. […]
55 min.